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Crystal
KTP
details

Potassium Titanyl Phosphate (KTiOPO3 or KTP) is widely used in both commercial and military lasers including laboratory and medical systems, range-finders, lidar, optical communication and industrial systems.

Table 1. Chemical and Structural properties


Crystal Structure

 Orthorhombic, space group Pna21,point group mm2

Lattice Parameter

 a=6.404?, b=10.616?, c=12.814?, Z=8

Melting Point   

 About 1172°C

Mohs Hardness   

 5

Density         

 3.01 g/cm3

Thermal Conductivity  

 13W/m/K

Thermal Expansion Coefficient

 αx=11x10-6/°C, αy=9x10-6/°C, αz=0.6x10-6/°C


Table 2. Optical and Nonlinear Optical Properties


Transparency Range

 3504500nm

SHG Phase Matchable Range

 4971800nm  (Type II)

Therm-optic Coefficients (/°C)

 dnx /dT=1.1X10-5
 dny/dT=1.3X10-5
 dnz/dT=1.6X10-5

Absorption  Coefficients

 <0.1%/cm at 1064nm    <1%/cm at 532nm

For Type II SHG of a Nd:YAG laser at 1064nm

 

 Temperature Acceptance: 24°C-cm
 Spectral Acceptance: 0.56nm-cm
 Angular Acceptance: 14.2mrad-cm (φ);55.3mrad-cm (θ)
 Walk-off Angle: 0.55°

NLO Coefficients

 deff(II)≈(d24-d15)sin2φsin2θ-(d15sin2φ + d24cos2φ)sinθ

Non-vanished NLO susceptibilities

 d31=6.5 pm/V    d24=7.6 pm/V
 d32=5 pm/V        d15=6.1 pm/V
 d33=13.7 pm/V

Sellmeier  Equations (λ in μm)

 nx2=3.0065+0.03901/(λ2-0.04251)-0.01327λ 2
 ny2=3.0333+0.04154/(λ 2-0.04547)-0.01408λ2
 nz2=3.3134+0.05694/(λ 2-0.05658)-0.01682λ2


AR-coating

● Dual Band AR-coating (DBAR) of KTP for SHG of 1064nm.
   low reflectance (R<0.2% at 1064nm and R<0.5% at 532nm );
   high damage threshold (>300MW/cm2 at both wavelengths);
   long durability.
● Broad Band AR-coating (BBAR) of KTP for OPO applications.
● High reflectivity coating: HR1064nm&HT532nm, R>99.8%@1064nm, T>90%@532nm.
● Other coatings are available upon request.


KTP Specifications:

● Dimension tolerance: (W±0.1mm)x(H±0.1mm)x(L+0.5/-0.1mm) (L≥2.5mm)
                                     (W±0.1mm)x(H±0.1mm)x(L+0.1/-0.1mm) (L<2.5mm)
● Clear aperture: central 90% of the diameter
● No visible scattering paths or centers when inspected by a 50mW green laser
● Flatness: less than λ/8 @ 633nm
● Transmitting wavefront distortion: less than λ/8 @ 633nm
● Chamfer: ≤0.2mm@45°
● Chip: ≤0.1mm
● Scratch/Dig code: better than 10/ 5 to MIL-PRF-13830B
● Parallelism: better than 20 arc seconds
● Perpendicularity: ≤5 arc minutes
● Angle tolerance: Δθ≤0.25°, Δφ≤0.25°
● Damage threshold[GW/cm ]: >0.5 for 1064nm, TEM00, 10ns, 10HZ (AR-coated)
                                                 >0.3 for 532nm, TEM00, 10ns, 10HZ (AR-coated)


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